Naphthotubes
Witryna蛋白质表现出高结合亲和力和选择性,以及卓越的催化性能。它们的结合口袋是疏水的,但也包含极性和带电基团,有助于极性有机分子在水溶液中的结合。在过去的几十年中,具有配备会聚极性基团的相当大的芳香腔的仿生受体的合成受到了相当大的关注。 Witryna20 wrz 2024 · Amide naphthotubes possess hydrogen bonding sites in their deep hydrophobic cavities and can effectively bind polar organic micropollutants in water …
Naphthotubes
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Witryna6 cze 2024 · By mimicking the binding pockets of bioreceptors, 43 we have developed a pair of macrocyclic hosts—amide naphthotubes—with hydrogen bonding donors inside their deep hydrophobic cavities. 44 – 48 These biomimetic hosts are able to selectively recognize a variety of organic molecules in water by combining the hydrophobic … Witryna12 cze 2024 · naphthotubes (NT; Figure 2a) are able to bind highly hydrophilic molecules in water by combining the hydro- phobic effec t with hydroge n bonding …
WitrynaAmide naphthotubes with four carboxylate sidechains have been reported by us to be able to selectively recognize hydrophilic molecules in water and have found applications in sensing and self ... Witryna2 dni temu · The preparation of new enantiopure tetrahedral cages enables the inclusion of steroids with high stereoselectivities. Subtle differences in cavity structure between cage enantiomers lead to major changes in guest binding affinity and even stoichiometry. Our work thus demonstrates how control over host handedness serves as a useful …
Witryna1 lut 2024 · He created a series of naphthol-based macrocyclic receptors well recognized as “naphthotubes” that have high binding selectivity in water. He demonstrated a simple and elegant design approach toward selectivity by introducing directional recognition sites into the inner-side of hydrophobic cavities. These recognition sites could be … Witryna21 lip 2024 · Naphthotubes with hydrogen-bond acceptors (ether, ester, and imine) prefer to bind organic cations; naphthotubes with hydrogen-bond donors (urea, thiourea, and amide) can bind neutral molecules ...
Witryna1 kwi 2024 · Drug molecules with multiple polar groups can be better accommodated by these naphthotubes. The anti -configured naphthotube show good biocompatibility …
Witryna7 kwi 2024 · Naphthotubes with hydrogen-bond acceptors (ether, ester, and imine) prefer to bind org. cations; naphthotubes with hydrogen-bond donors (urea, thiourea, and amide) can bind neutral mols.; amine naphthotubes are stimuli-responsive to acid/base. In particular, the water-sol. amide naphthotubes are able to selectively … settings on fitbit charge 4WitrynaThe unique recognition ability of these naphthotubes provides the basis for their applications in sensing, self-assembly, and molecular machines. Fluorescent sensing … the times port royal paWitryna7 wrz 2016 · The thiourea NaphthoTubes 25 generally show better binding ability than the urea NaphthoTubes 24. These endo-functionalized NaphthoTubes are highly reminiscent of enzyme binding pockets. Provided water-soluble groups are installed, these NaphthoTubes may be applied to supramolecular catalysis and molecular … settings on firestick remoteWitrynaIn this research, we reported a new class of macrocyclic hosts, namely methylene-bridged naphthotubes, with well-defined cavities. They were synthesized through … settings on fire 8WitrynaNephrostomy Tube. A nephrostomy (neff ROSS toh mee) tube is a tube that is put into the kidney to drain urine directly from the kidney. Urine is made by the kidneys and … the times portugalWitryna15 paź 2024 · In this study, we investigated the volumetric properties for the binding of 1,4-dioxane to a pair of naphthotubes (i.e., anti- and syn-isomers), each possessing two inwardly directed amide groups in the hydrophobic cavity, using nuclear magnetic resonance and fluorescence spectroscopy coupled with pressure perturbation. the times porter countyWitryna2 lis 2024 · Benzene hydrogenation is an important industrial process. The reaction is incomplete, resulting in a mixture of benzene, cyclohexane, and/or cyclohexene that … the times postal address